{"id":26161,"date":"2024-06-05T10:51:07","date_gmt":"2024-06-05T02:51:07","guid":{"rendered":"\/phys\/?post_type=tkuisotope&#038;p=26161"},"modified":"2026-03-03T14:42:08","modified_gmt":"2026-03-03T06:42:08","slug":"%e8%8e%8a%e7%a8%8b%e8%b1%aa-black-phosphorus-composites-with-engineered-interfaces-for-high-rate-high-capacity-lithium-storage","status":"publish","type":"tkuisotope","link":"\/phys\/?tkuisotope=%e8%8e%8a%e7%a8%8b%e8%b1%aa-black-phosphorus-composites-with-engineered-interfaces-for-high-rate-high-capacity-lithium-storage","title":{"rendered":"Black phosphorus composites with engineered interfaces for high-rate high-capacity lithium storage (\u838a\u7a0b\u8c6a)\u5177\u4ecb\u9762\u5de5\u7a0b\u8a2d\u8a08\u7684\u9ed1\u78f7\u8907\u5408\u6750\u6599\uff0c\u5be6\u73fe\u9ad8\u500d\u7387\u3001\u9ad8\u5bb9\u91cf\u92f0\u5132\u5b58"},"content":{"rendered":"\n<div class=\"wp-block-tkuwpbs5-bs5-container container\" style=\"position:relative\" block_id=\"mc1j380i6jk1a4g1eke\"><style><\/style>\n<div class=\"wp-block-tkuwpbs5-bs5-row row\">\n<div class=\"wp-block-tkuwpbs5-bs5-column col-md-12 align-self-start\">\n<p class=\"has-background has-medium-font-size\" style=\"background-color:#abb7c296\">Hongchang Jin; Sen Xin,<strong><span style=\"color: #9b51e0;\" class=\"stk-highlight\"> Chenghao Chuang<\/span><\/strong>; Wangda Li; Haiyun Wang; Jian Zhu; Huanyu Xie; Taiming Zhang; Yangyang Wan; Zhikai Qi; Wensheng Yan; Ying-Rui Lu; Ting-Shan Chan; Xiaojun Wu; John B. Goodenough; Hengxing Ji; Xiangfeng Duan <strong><em>SCIENCE<\/em><\/strong> 370(6513), p.192-197<\/p>\n<\/div>\n\n\n\n<div class=\"wp-block-tkuwpbs5-bs5-column col-md-12 align-self-start\">\n<p class=\"has-medium-font-size\"><strong>\u8ad6\u6587\u5168\u6587: <a rel=\"noreferrer noopener\" href=\"https:\/\/www.science.org\/doi\/10.1126\/science.aav5842\" data-type=\"link\" data-id=\"https:\/\/www.science.org\/doi\/10.1126\/science.aav5842\" target=\"_blank\">https:\/\/www.science.org\/doi\/10.1126\/science.aav5842<\/a><\/strong><\/p>\n<\/div>\n\n\n\n<div class=\"wp-block-tkuwpbs5-bs5-column col-md-12 align-self-start\">\n<p class=\"has-medium-font-size\" style=\"line-height:1.8\">        \u900f\u7531\u300c\u81e8\u5834X\u5149\u5438\u6536\u5149\u8b5c\uff08Operando X-ray absorption spectroscopy\uff09\u6280\u8853\u548c\u9ad8\u9748\u654f\u77fd\u504f\u79fb\u5075\u6e2c\u5668(Silicon drift detector)\uff0c\u5373\u6642\u9396\u5b9a\u78f7\u5143\u7d20\u7684\u5438\u6536\u5149\u8b5c\uff0c\u5728\u5916\u754c\u96fb\u5316\u5b78\u5145\u653e\u96fb\u689d\u4ef6\u4e0b\uff0c\u767c\u73fe\u4ecb\u9762\u5b58\u5728\u65b0\u92f0\u78f7(LiP)\u5316\u5b78\u9375\uff0c\u4e26\u6539\u8b8a\u5176\u9ed1\u78f7\u6c27\u5316\u50f9\u614b\uff0cX\u5149\u5438\u6536\u8b5c\u4f50\u8b49\u65b0\u5316\u5b78\u9375(P<img decoding=\"async\" loading=\"lazy\" width=\"14\" height=\"18\" src=\"\">LiP<img decoding=\"async\" loading=\"lazy\" width=\"14\" height=\"18\" src=\"\">Li2P<img decoding=\"async\" loading=\"lazy\" width=\"14\" height=\"18\" src=\"\">Li<sub>3<\/sub>P)\u6c27\u5316\u9084\u539f\u7684\u52d5\u614b\u8b8a\u5316\uff0c\u53ef\u5c0d\u61c9\u5230\u5373\u6642\u92f0\u96e2\u5b50\u5d4c\u5165\u548c\u5d4c\u51fa\u884c\u70ba\u3002\u6750\u6599\u5408\u6210\u7279\u6b8a\u6027\u4f86\u81ea\u65bc\u5c64\u72c0\u9ed1\u78f7\u908a\u754c\u63a5\u9644\u65bc\u5c64\u72c0\u77f3\u58a8\u908a\u754c\u4e0a\uff0c\u800c\u5916\u90e8\u81a0\u72c0\u805a\u82ef\u80fa\u7a69\u5b9a\u4f4f\u9ed1\u78f7\u77f3\u58a8\u5948\u7c73\u7403\u5167\u90e8\u5f62\u72c0\uff0c\u81a0\u72c0\u5948\u7c73\u5c64\u89d2\u8272\u70ba\u63d0\u4f9b\u9577\u6548\u4e14\u5feb\u901f\u5145\u653e\u96fb\u7684\u56fa\u6db2\u908a\u754c\u5c64(solid-electrolyte interohase); 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eV)\uff0c\u907a\u61be\u7684\u662f\u6700\u65b0\u5be6\u9a57\u4ecd\u7121\u6cd5\u9054\u5230\u5176\u7406\u8ad6\u503c\u9ad8\u5ea6\uff1b\u56e0\u6b64\u6211\u5011\u6df7\u548c\u9ed1\u78f7\u8207\u77f3\u58a8\u5c64\u72c0\u7269\u4f86\u53d6\u4ee3\u55ae\u4e00\u8ca0\u6975\u77f3\u58a8\u7247\uff0c\u517c\u9867\u9ad8\u92f0\u96e2\u5b50\u5132\u5b58\u91cf\u548c\u5feb\u901f\u9ad8\u5145\u653e\u96fb\u512a\u9ede\uff0c\u6e2c\u8a66\u7d50\u679c\u767c\u73fe\uff0c\u9078\u5b9a\u9ad8\u96fb\u6d41(13A\/g)\u60c5\u6cc1\uff0c\u53ef\u5faa\u74b0\u96fb\u80fd\u5bb9\u91cf\u4ecd\u5230\u9054350 mAh\/g\uff0c\u610f\u5473\u8457\u53ea\u9700\u8981\u7d04\u5169\u5206\u9418\u5c07\u53ef\u5145\u98fd\u9ed1\u78f7\u96fb\u6c60\uff0c\u800c\u5176\u96fb\u80fd\u5bb9\u91cf\u6bd4\u7279\u65af\u62c9model 3\u7cfb\u5217\u96fb\u52d5\u8eca\u96fb\u6c60(74 mAh\/g)\u9ad8\u4e0a\u7d04\u4e94\u500d\uff0c\u4f46\u7279\u65af\u62c9model 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Jin; Sen Xin, Chenghao Chuang; Wangda Li; Haiyun Wang; Jian Zhu; Huanyu Xie; Taiming Zhang; Yangyang Wan; Zhikai Qi; Wensheng Yan; Ying-Rui Lu; Ting-Shan Chan; Xiaojun Wu; John B. Goodenough; Hengxing Ji; Xiangfeng Duan SCIENCE 370(6513), p.192-197 \u8ad6\u6587\u5168\u6587: https:\/\/www.science.org\/doi\/10.1126\/science.aav5842 \u900f\u7531\u300c\u81e8\u5834X\u5149\u5438\u6536\u5149\u8b5c\uff08Operando X-ray absorption spectroscopy\uff09\u6280\u8853\u548c\u9ad8\u9748\u654f\u77fd\u504f\u79fb\u5075\u6e2c\u5668(Silicon drift detector)\uff0c\u5373\u6642\u9396\u5b9a\u78f7\u5143\u7d20\u7684\u5438\u6536\u5149\u8b5c\uff0c\u5728\u5916\u754c\u96fb\u5316\u5b78\u5145\u653e\u96fb\u689d\u4ef6\u4e0b\uff0c\u767c\u73fe\u4ecb\u9762\u5b58\u5728\u65b0\u92f0\u78f7(LiP)\u5316\u5b78\u9375\uff0c\u4e26\u6539\u8b8a\u5176\u9ed1\u78f7\u6c27\u5316\u50f9\u614b\uff0cX\u5149\u5438\u6536\u8b5c\u4f50\u8b49\u65b0\u5316\u5b78\u9375(PLiPLi2PLi3P)\u6c27\u5316\u9084\u539f\u7684\u52d5\u614b\u8b8a\u5316\uff0c\u53ef\u5c0d\u61c9\u5230\u5373\u6642\u92f0\u96e2\u5b50\u5d4c\u5165\u548c\u5d4c\u51fa\u884c\u70ba\u3002\u6750\u6599\u5408\u6210\u7279\u6b8a\u6027\u4f86\u81ea\u65bc\u5c64\u72c0\u9ed1\u78f7\u908a\u754c\u63a5\u9644\u65bc\u5c64\u72c0\u77f3\u58a8\u908a\u754c\u4e0a\uff0c\u800c\u5916\u90e8\u81a0\u72c0\u805a\u82ef\u80fa\u7a69\u5b9a\u4f4f\u9ed1\u78f7\u77f3\u58a8\u5948\u7c73\u7403\u5167\u90e8\u5f62\u72c0\uff0c\u81a0\u72c0\u5948\u7c73\u5c64\u89d2\u8272\u70ba\u63d0\u4f9b\u9577\u6548\u4e14\u5feb\u901f\u5145\u653e\u96fb\u7684\u56fa\u6db2\u908a\u754c\u5c64(solid-electrolyte interohase); \u5145\u96fb\u904e\u7a0b\u4e2d\u96fb\u5b50\u8f49\u79fb\u9032\u5c0e\u96fb\u9ed1\u78f7\u77f3\u58a8\u5948\u7c73\u7403\uff0c\u6db2\u9ad4\u4e2d\u92f0\u96e2\u5b50\u7a7f\u904e\u81a0\u72c0\u5c64\u5f8c\u518d\u8207\u9ed1\u78f7\u5c64\u9375\u7d50\uff0c\u56e0\u5167\u90e8\u9ed1\u78f7\u8207\u77f3\u58a8\u5f62\u6210\u826f\u597d\u7d50\u69cb\u7a69\u5b9a\u6027\uff0c\u9664\u4e86\u63d0\u4f9b\u66f4\u591a\u5145\u653e\u96fb\u5bb9\u91cf\u5340\u584a\uff0c\u9ed1\u78f7\u4ecb\u9762\u4e5f\u64c1\u6709\u8f03\u4f4e\u92f0\u96e2\u5b50\u79fb\u52d5\u80fd\u91cf\uff0c\u56e0\u800c\u5f62\u6210\u8d85\u5feb\u5145\u96fb\u6548\u7387\u3002 \u8a72\u8ad6\u6587\u8457\u91cd\u65bc\u65b0\u7a4e\u9ed1\u78f7\u6750\u6599\u5408\u6210\uff0c\u540c\u6b65\u8f3b\u5c04\u81e8\u5834\u5149\u6e90\u63a2\u6e2c\uff0c\u548c\u7406\u8ad6\u4ecb\u9762\u9375\u7d50\u80fd\u91cf\uff0c\u5176\u8de8\u570b\u5408\u4f5c\u6210\u679c\u7372\u5f97\u6975\u5927\u7684\u96fb\u6c60\u9818\u57df\u7a81\u7834\u3002 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