{"id":28936,"date":"2024-11-25T15:15:44","date_gmt":"2024-11-25T07:15:44","guid":{"rendered":"\/phys\/?post_type=tkuisotope&#038;p=28936"},"modified":"2026-03-03T14:53:01","modified_gmt":"2026-03-03T06:53:01","slug":"direct-identification-of-o-o-bond-formation-through-three-step-oxidation-during-water-splitting-by-operando-soft-x-ray-absorption-spectroscopy-%e8%91%a3%e5%b4%87%e7%a6%ae","status":"publish","type":"tkuisotope","link":"\/phys\/?tkuisotope=direct-identification-of-o-o-bond-formation-through-three-step-oxidation-during-water-splitting-by-operando-soft-x-ray-absorption-spectroscopy-%e8%91%a3%e5%b4%87%e7%a6%ae","title":{"rendered":"Direct Identification of O-O Bond Formation Through Three-Step Oxidation During Water Splitting by Operando Soft X-ray Absorption Spectroscopy (\u8463\u5d07\u79ae)\u901a\u904e\u539f\u4f4d\u8edfX\u5149\u5438\u6536\u5149\u8b5c\u76f4\u63a5\u89c0\u6e2c\u6c34\u5206\u89e3\u904e\u7a0b\u4e2dO-O\u9375\u7684\u5f62\u6210\u8207\u4e09\u968e\u6bb5\u6c27\u5316\u6b65\u9a5f"},"content":{"rendered":"\n<div class=\"wp-block-tkuwpbs5-bs5-container container\" style=\"position:relative\" block_id=\"mc1o5lhxvn2r1y3j\"><style><\/style>\n<div class=\"wp-block-tkuwpbs5-bs5-row row\">\n<div class=\"wp-block-tkuwpbs5-bs5-column col-md-12 align-self-start\">\n<p class=\"has-background\" style=\"background-color:#abb7c270\">Yu-Cheng Huang, Yujie Wu, Ying-Rui Lu, Jeng-Lung Chen, Hong-Ji Lin, Chien-Te Chen, Chi-Liang Chen, Chao Jing, Jing Zhou, Linjuan Zhang, Yanyong Wang, Wu-Ching Chou,* Shuangyin Wang,* Zhiwei Hu,* and <strong><span style=\"color: #9b51e0;\" class=\"stk-highlight\">Chung-Li Dong*<\/span><\/strong>, Advanced Science 2024, 11, 2401236<\/p>\n<\/div>\n\n\n\n<div class=\"wp-block-tkuwpbs5-bs5-column col-md-12 align-self-start\">\n<p class=\"has-medium-font-size\"><strong>\u984c\u76ee : \u901a\u904e\u539f\u4f4d\u8edfX\u5149\u5438\u6536\u5149\u8b5c\u76f4\u63a5\u89c0\u6e2c\u6c34\u5206\u89e3\u904e\u7a0b\u4e2dO-O\u9375\u7684\u5f62\u6210\u8207\u4e09\u968e\u6bb5\u6c27\u5316\u6b65\u9a5f<\/strong><\/p>\n\n\n\n<p class=\"has-medium-font-size\">\u8ad6\u6587\u5168\u6587:<a href=\"https:\/\/doi.org\/10.1002\/advs.202401236\">https:\/\/doi.org\/10.1002\/advs.202401236<\/a><\/p>\n<\/div>\n\n\n\n<div class=\"wp-block-tkuwpbs5-bs5-column col-md-6 align-self-start\">\n<div class=\"wp-block-stackable-image stk-block-image stk-block stk-d3969b1\" data-block-id=\"d3969b1\"><figure><span class=\"stk-img-wrapper stk-image--shape-stretch\"><img decoding=\"async\" loading=\"lazy\" class=\"stk-img wp-image-28939\" src=\"\/phys\/wp-content\/uploads\/2024\/11\/\u84632024112502.png\" width=\"588\" height=\"408\" srcset=\"\/phys\/wp-content\/uploads\/2024\/11\/\u84632024112502.png 588w, \/phys\/wp-content\/uploads\/2024\/11\/\u84632024112502-300x208.png 300w\" sizes=\"(max-width: 588px) 100vw, 588px\" \/><\/span><\/figure><\/div>\n<\/div>\n\n\n\n<div class=\"wp-block-tkuwpbs5-bs5-column col-md-6 align-self-start\">\n<p class=\"has-medium-font-size\" style=\"line-height:1.8\">        \u5728\u9019\u7bc7\u6750\u6599\u754c\u7b2c\u4e00\u540d\u671f\u520a(Advanced Materials)\u6587\u7ae0\u4e2d\uff0c\u5229\u7528\u4e8c\u7dad\u6750\u6599WS\u2082\u8d85\u6676\u683c\u4f86\u652f\u6490\u91d1(Au)\u5948\u7c73\u5718\u4ee5\u53ca\u91d5(Ru)\u55ae\u539f\u5b50\uff0c\u4f86\u986f\u8457\u63d0\u5347\u6c2b\u6c23\u751f\u6210\u53cd\u61c9\uff08Hydrogen Evolution Reaction, HER\uff09\u7684\u6548\u7387\u3002\u6b64\u7814\u7a76\u7684\u95dc\u9375\u767c\u73fe\u5728\uff0c\u5c07Au\u5948\u7c73\u5718\u548cRu\u55ae\u539f\u5b50\u5206\u4f48\u5728WS\u2082\u96d9\u5c64\u8d85\u6676\u683c\u4e2d\uff0c\u5f62\u6210\u4e00\u7a2e\u7a69\u5b9a\u7684\u591a\u5b54\u7d50\u69cb\u3002\u9019\u7a2e\u7d50\u69cb\u901a\u904e\u91d1\u5c6c\u539f\u5b50-\u652f\u6490\u6750\u6599\u4e4b\u9593\u7684\u96fb\u5b50\u4ea4\u4e92\u4f5c\u7528(Electronic Metal\u2013Support Interaction, EMSI)\u512a\u5316\u4e86\u96fb\u8377\u5206\u4f48\uff0c\u6709\u6548\u5730\u964d\u4f4e\u4e86\u6c34\u5438\u9644\u7684\u80fd\u91cf\u969c\u7919\uff0c\u5f9e\u800c\u4fc3\u9032\u4e86H\u2082\u7684\u751f\u6210\u3002\u540c\u6b65\u8f3b\u5c04X\u5149\u6280\u8853\u5728\u6b64\u7814\u7a76\u4e2d\u626e\u6f14\u4e86\u4e0d\u53ef\u6216\u7f3a\u7684\u89d2\u8272\uff0c\u63d0\u4f9b\u4e86\u7cbe\u78ba\u7684\u81e8\u5834\u89c0\u6e2c\u624b\u6bb5\uff0c\u5f97\u4ee5\u5be6\u6642\u8ffd\u8e64\u5728HER\u50ac\u5316\u53cd\u61c9\u4e2d\u7684Au\u8207Ru\u7684\u539f\u5b50\u74b0\u5883\u4ee5\u53ca\u96fb\u8377\u8f49\u79fb\u4e4b\u9593\u7684\u8b8a\u5316\uff0c\u9032\u800c\u63a2\u8a0e\u9019\u4e9b\u91d1\u5c6c\u539f\u5b50\u5728\u4e0d\u540c\u53cd\u61c9\u689d\u4ef6\u4e0b\u7684\u52d5\u614b\u884c\u70ba\u3002\u901a\u904e\u81e8\u5834X\u5c04\u7dda\u5438\u6536\u5149\u8b5c(X-ray Absorption Spectroscopy, XAS)\uff0c\u7814\u7a76\u5718\u968a\u80fd\u5920\u89c0\u5bdf\u5230Ru\u5728HER\u904e\u7a0b\u4e2d\u5f9e\u8f03\u9ad8\u7684\u6c27\u5316\u614b\u9010\u6b65\u964d\u4f4e\uff0c\u9019\u6697\u793a\u5176\u5728\u53cd\u61c9\u4e2d\u6709\u6548\u4fc3\u9032\u6c34\u5206\u5b50\u7684\u89e3\u96e2\u3002<\/p>\n\n\n\n<p class=\"has-medium-font-size\" style=\"line-height:1.8\">        \u6b64\u5916\uff0cAu\u539f\u5b50\u7684\u6c27\u5316\u614b\u5728\u53cd\u61c9\u904e\u7a0b\u4e2d\u4e5f\u767c\u751f\u8b8a\u5316\uff0c\u6301\u7e8c\u63d0\u4f9b\u96fb\u5b50\u4f86\u7a69\u5b9aRu\u7684\u6d3b\u6027\u4f4d\uff0c\u9632\u6b62\u5176\u5728\u50ac\u5316\u904e\u7a0b\u4e2d\u5931\u53bb\u6d3b\u6027\u3002\u9019\u4e9b\u767c\u73fe\u5fc5\u9808\u900f\u904e\u5148\u9032\u7684\u540c\u6b65\u8f3b\u5c04\u81e8\u5834XAS\u7684\u5f97\u4ee5\u8a73\u7d30\u4e86\u89e3\uff0c\u4e5f\u8b93\u6211\u5011\u4e86\u89e3\u5230\u5728\u9019\u6700\u65b0\u7a4e\u7684\u9ad8\u6548\u7387\u50ac\u5316\u4e8c\u7dad\u6750\u6599HER\u53cd\u61c9\u7684\u6a5f\u5236\u3002<\/p>\n<\/div>\n<\/div>\n<\/div>\n","protected":false},"author":10,"template":"wp-custom-template-detail-4-post","meta":{"_uag_custom_page_level_css":""},"categories":[103],"tags":[],"acf":[],"featured_image_urls":{"full":"","thumbnail":"","medium":"","medium_large":"","large":"","twp-icon":"","1536x1536":"","2048x2048":""},"post_excerpt_stackable":"<p>Yu-Cheng Huang, Yujie Wu, Ying-Rui Lu, Jeng-Lung Chen, Hong-Ji Lin, Chien-Te Chen, Chi-Liang Chen, Chao Jing, Jing Zhou, Linjuan Zhang, Yanyong Wang, Wu-Ching Chou,* Shuangyin Wang,* Zhiwei Hu,* and Chung-Li Dong*, Advanced Science 2024, 11, 2401236 \u984c\u76ee : \u901a\u904e\u539f\u4f4d\u8edfX\u5149\u5438\u6536\u5149\u8b5c\u76f4\u63a5\u89c0\u6e2c\u6c34\u5206\u89e3\u904e\u7a0b\u4e2dO-O\u9375\u7684\u5f62\u6210\u8207\u4e09\u968e\u6bb5\u6c27\u5316\u6b65\u9a5f \u8ad6\u6587\u5168\u6587:https:\/\/doi.org\/10.1002\/advs.202401236 \u5728\u9019\u7bc7\u6750\u6599\u754c\u7b2c\u4e00\u540d\u671f\u520a(Advanced Materials)\u6587\u7ae0\u4e2d\uff0c\u5229\u7528\u4e8c\u7dad\u6750\u6599WS\u2082\u8d85\u6676\u683c\u4f86\u652f\u6490\u91d1(Au)\u5948\u7c73\u5718\u4ee5\u53ca\u91d5(Ru)\u55ae\u539f\u5b50\uff0c\u4f86\u986f\u8457\u63d0\u5347\u6c2b\u6c23\u751f\u6210\u53cd\u61c9\uff08Hydrogen Evolution Reaction, HER\uff09\u7684\u6548\u7387\u3002\u6b64\u7814\u7a76\u7684\u95dc\u9375\u767c\u73fe\u5728\uff0c\u5c07Au\u5948\u7c73\u5718\u548cRu\u55ae\u539f\u5b50\u5206\u4f48\u5728WS\u2082\u96d9\u5c64\u8d85\u6676\u683c\u4e2d\uff0c\u5f62\u6210\u4e00\u7a2e\u7a69\u5b9a\u7684\u591a\u5b54\u7d50\u69cb\u3002\u9019\u7a2e\u7d50\u69cb\u901a\u904e\u91d1\u5c6c\u539f\u5b50-\u652f\u6490\u6750\u6599\u4e4b\u9593\u7684\u96fb\u5b50\u4ea4\u4e92\u4f5c\u7528(Electronic Metal\u2013Support Interaction, EMSI)\u512a\u5316\u4e86\u96fb\u8377\u5206\u4f48\uff0c\u6709\u6548\u5730\u964d\u4f4e\u4e86\u6c34\u5438\u9644\u7684\u80fd\u91cf\u969c\u7919\uff0c\u5f9e\u800c\u4fc3\u9032\u4e86H\u2082\u7684\u751f\u6210\u3002\u540c\u6b65\u8f3b\u5c04X\u5149\u6280\u8853\u5728\u6b64\u7814\u7a76\u4e2d\u626e\u6f14\u4e86\u4e0d\u53ef\u6216\u7f3a\u7684\u89d2\u8272\uff0c\u63d0\u4f9b\u4e86\u7cbe\u78ba\u7684\u81e8\u5834\u89c0\u6e2c\u624b\u6bb5\uff0c\u5f97\u4ee5\u5be6\u6642\u8ffd\u8e64\u5728HER\u50ac\u5316\u53cd\u61c9\u4e2d\u7684Au\u8207Ru\u7684\u539f\u5b50\u74b0\u5883\u4ee5\u53ca\u96fb\u8377\u8f49\u79fb\u4e4b\u9593\u7684\u8b8a\u5316\uff0c\u9032\u800c\u63a2\u8a0e\u9019\u4e9b\u91d1\u5c6c\u539f\u5b50\u5728\u4e0d\u540c\u53cd\u61c9\u689d\u4ef6\u4e0b\u7684\u52d5\u614b\u884c\u70ba\u3002\u901a\u904e\u81e8\u5834X\u5c04\u7dda\u5438\u6536\u5149\u8b5c(X-ray Absorption Spectroscopy, XAS)\uff0c\u7814\u7a76\u5718\u968a\u80fd\u5920\u89c0\u5bdf\u5230Ru\u5728HER\u904e\u7a0b\u4e2d\u5f9e\u8f03\u9ad8\u7684\u6c27\u5316\u614b\u9010\u6b65\u964d\u4f4e\uff0c\u9019\u6697\u793a\u5176\u5728\u53cd\u61c9\u4e2d\u6709\u6548\u4fc3\u9032\u6c34\u5206\u5b50\u7684\u89e3\u96e2\u3002 \u6b64\u5916\uff0cAu\u539f\u5b50\u7684\u6c27\u5316\u614b\u5728\u53cd\u61c9\u904e\u7a0b\u4e2d\u4e5f\u767c\u751f\u8b8a\u5316\uff0c\u6301\u7e8c\u63d0\u4f9b\u96fb\u5b50\u4f86\u7a69\u5b9aRu\u7684\u6d3b\u6027\u4f4d\uff0c\u9632\u6b62\u5176\u5728\u50ac\u5316\u904e\u7a0b\u4e2d\u5931\u53bb\u6d3b\u6027\u3002\u9019\u4e9b\u767c\u73fe\u5fc5\u9808\u900f\u904e\u5148\u9032\u7684\u540c\u6b65\u8f3b\u5c04\u81e8\u5834XAS\u7684\u5f97\u4ee5\u8a73\u7d30\u4e86\u89e3\uff0c\u4e5f\u8b93\u6211\u5011\u4e86\u89e3\u5230\u5728\u9019\u6700\u65b0\u7a4e\u7684\u9ad8\u6548\u7387\u50ac\u5316\u4e8c\u7dad\u6750\u6599HER\u53cd\u61c9\u7684\u6a5f\u5236\u3002<\/p>\n","category_list":"<a href=\"\/phys\/?cat=103\" rel=\"category\">journal<\/a>","author_info":{"name":"\u9ec3\u9806\u8208","url":"\/phys\/?author=10"},"comments_num":"0 comments","uagb_featured_image_src":[],"uagb_author_info":{"display_name":"\u9ec3\u9806\u8208","author_link":"\/phys\/?author=10"},"uagb_comment_info":0,"uagb_excerpt":null,"_links":{"self":[{"href":"\/phys\/index.php?rest_route=\/wp\/v2\/tkuisotope\/28936"}],"collection":[{"href":"\/phys\/index.php?rest_route=\/wp\/v2\/tkuisotope"}],"about":[{"href":"\/phys\/index.php?rest_route=\/wp\/v2\/types\/tkuisotope"}],"author":[{"embeddable":true,"href":"\/phys\/index.php?rest_route=\/wp\/v2\/users\/10"}],"wp:attachment":[{"href":"\/phys\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=28936"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/phys\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=28936"},{"taxonomy":"post_tag","embeddable":true,"href":"\/phys\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=28936"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}